How do I easily transfer Outlook 2010 settings, etc. to a new pc?

I have an Outlook 2010 setup with about 8 email accounts as well as two large .pst files, one of which is an archive file that is over 4GB is size, as well as many rule settings and folders. What would be the best way to transfer my settings to a new pc? I have ready that Windows Easy Transfer might be the way to go. I have also read instructions on how to manually transfer the files over. What is best?