How do I move photos that are stored in the cell phone (stored on "device") onto a new memory card?

I have a Samsung Galaxy 4 and I recently exceeded the storage space on the old memory card. The phone was storing photos onto the device for a short time. I didn’t realize that until I took the card out in order to get the photos printed and saw that the storage of the old card was exceeded and phone was automatically storing them onto device.

I recently got a new memory card and would like to move those photos, if possible, onto the card.

Is that possible and if so, how?

If not, what I really want to do is upload those photos to social network or at the very least, be able to just print them and/or save them onto a disc.