My 13 year old daughter has never seen a James Bond movie. Which one should I show her to introduce her to the series?

Skyfall was available on Netflix streaming, but I don’t think that’s a good one to start off with, since it makes a bunch of assumptions about the character that you already know. I’m thinking one of the Pierce Bronson ones because it introduces Judi Dench as M, but if you think one of the older ones would be better, then I’ll go with that.